4-methyl-4-[2-(naphthalene)-2-oxoethyl] morpholin-4-ium iodide as a water soluble photoinitiator
نویسندگان
چکیده
Quaternary ammonium salt namely 4-methyl-4-[2-(naphthalen-2-yl)-2-oxoethyl] morpholin-4-ium iodide (WSMPM) was synthesized and characterized. High molar absorptivity at 347 nm (1910 L･mol-1･cm-1) good solubility in distilled water (10-2 M) allows WSMPM to be used as an effective photoinitiator also water-soluble systems. Photopolymerization of acrylamide monomer with (10-3 a tertiary amine (N-methyldiethanolamine), resulted 84.4% polymer conversion. Based on laser photolysis electron spin resonance, mechanism proposed.
منابع مشابه
4-[(2′-Cyanobiphenyl-4-yl)methyl]morpholin-4-ium nitrate
The title ion pair, C(18)H(19)N(2)O(+)·NO(3) (-), features an N-H⋯O hydrogen bond linking the cation to the anion. The morpholine portion adopts a chair conformation; the aromatic rings of the biphenyl-ene portion are twisted [torsion angles for the four atoms involving the ar-yl-aryl bond = 35.1 (2)-40.4 (2)°].
متن کامل4-[(2′-Cyanobiphenyl-4-yl)methyl]morpholin-4-ium perchlorate
In the title salt, C(18)H(19)N(2)O(+)·ClO(4) (-), the morpholinium ring adopts a chair conformation, while the two benzene rings make a dihedral angle of 62.65 (17)°. Inter-molecular N-H⋯N hydrogen bonds and weak C-H⋯O inter-actions occur in the crystal structure.
متن کامل4-[(2′-Cyanobiphenyl-4-yl)methyl]morpholin-4-ium hexafluoridophosphate
In the cation of the title compound, C(18)H(19)N(2)O(+)·PF(6) (-), the morpholine ring adopts the usual chair conformation and the dihedral angle between the benzene rings is 67.55 (11)°. The F atoms of the anion are disordered over two orientations with a refined occupancy ratio of 0.65 (2):0.35 (2). In the crystal, inter-molecular N-H⋯N hydrogen bonds link the cations into chains parallel to ...
متن کامل4-[(2′-Cyanobiphenyl-4-yl)methyl]morpholin-4-ium tetrafluoridoborate
In the crystal structure of the title compound, C(18)H(19)N(2)O(+)·BF(4) (-), bifurcated N-H⋯(F,F) hydrogen bonds link the protonated 4'-morpholine-methyl-biphenyl-2-carbonitrile cations and slightly distorted tetra-fluoro-borate anions. π-π inter-actions [centroid-centroid distance = 3.805 (3) Å] help to consolidate the packing. The dihedral angle between the benzene rings in the cation is 57....
متن کامل(E)-2-[2-(4-Chlorobenzylidene)hydrazinyl]-4-[3-(morpholin-4-ium-4-yl)propylamino]quinazolin-1-ium bis(perchlorate)
In the title compound, C(22)H(27)ClN(6)O(2) (2+)·2ClO(4) (-), the mol-ecule adopts an E conformation about the C=N double bond. The quinazoline ring is approximately planar, with an r.m.s. deviation of 0.0432 Å, and forms a dihedral angle of 5.77 (4)° with the chloro-phenyl ring. The crystal packing features N-H⋯O hydrogen bonds.
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ژورنال
عنوان ژورنال: Polimery
سال: 2023
ISSN: ['0032-2725']
DOI: https://doi.org/10.14314/polimery.2023.4.3